Silane Coupling Agent
Silane coupling agent introduction
A silane coupling agent is a chemical compound that contains both organic functional groups and inorganic functional groups. These compounds act as a bridge between organic and inorganic materials, improving the adhesion and compatibility between different materials. Silane coupling agents play a crucial role in improving the performance and durability of materials in a wide range of industrial applications.
Silanization of glass
This process involves the formation of a covalent bond between the silane molecules and the glass surface. This is typically achieved through a chemical reaction where the silane’s reactive groups (like alkoxy groups – methoxy or ethoxy) hydrolyze to form silanol groups that can then bond with the hydroxyl groups present on the glass surface. Glass silanization results a cross-linked, organofunctionalized layer on the glass that modifies its surface properties. Silanized glass provides enhanced surface properties that are advantageous across a range of scientific, industrial, and medical applications.
Adhesives and Sealants
- Bond Strength: Silane coupling agents are used to improve the adhesion of adhesives and sealants to different substrates.
- Moisture Resistance: They also provide improved moisture resistance, enhancing the durability of the bond in harsh environments.
Rubber and Tire Industry
- Reinforcement: Silane coupling agents enhance the dispersion and adhesion of fillers (e.g., silica) in rubber and plastic compounds, leading to improved mechanical properties such as tensile strength and abrasion resistance.
- Crosslinking: They can act as crosslinking agents, improving the heat resistance and stability of rubber such as in tire manufacturing.
Coatings and Paints
- Adhesion Promotion: In coatings and paints, silane coupling agents enhance adhesion to various surfaces to improve coating adhesion.
- Corrosion Resistance: Extend the life of coated materials.
Silane coupling agent product list
| Functional Group | Chemical Name | Cas No. |
|---|---|---|
| Amino | 3-Aminopropyltriethoxysilane | 919-30-2 |
| 3-Aminopropyltrimethoxysilane | 13822-56-5 | |
| N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane | 1760-24-3 | |
| 3-(2-Aminoethylamino)propyldimethoxymethylsilane | 3069-29-2 | |
| (3-Anilinopropyl)trimethoxysilane | 3068-76-6 | |
| Epoxy | 3-Glycidyloxypropyltriethoxysilane | 2602-34-8 |
| 3-Glycidyloxypropyltrimethoxysilane | 2530-83-8 | |
| 3-Glycidoxypropyldimethoxymethylsilane | 65799-47-5 | |
| 3-Glycidyloxypropylmethylsilane | 2897-60-1 | |
| 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane | 3388-04-03 | |
| 2-(3,4-Epoxycyclohexyl)ethyltriethoxysilane | 10217-34-2 | |
| Methacryloxy | 3-Methacryloyloxypropyltrimethoxysilane | 2530-85-0 |
| 3-Methacryloxypropylmethyldimethoxysilane | 14513-34-9 | |
| Vinyl | Vinyltriethoxysilane | 78-08-0 |
| Vinyltrimethoxysilane | 2768-02-07 | |
| Vinyltris(isopropenoxy)silane | 15332-99-7 | |
| Vinyltris(2-methoxyethoxy)silane | 1067-53-4 | |
| Sulfur | Bis(3-triethoxysilylpropyl)tetrasulfide | 40372-72-3 |
| Bis(3-triethoxysilylpropyl)disulfane | 56706-10-6 | |
| 3-Mercaptopropyltrimethoxysilane | 4420-74-0 | |
| 3-Thiocyanatopropyltriethoxysilane | 34708-08-02 | |
| Ureid | 3-Ureidopropyltrimethoxysilane | 23843-64-3 |
| 3-Ureidopropyltriethoxysilane | 23779-32-0 | |
| Isocyante | 3-Isocyanatepropyltriethoxysilane | 24801-88-5 |
| 3-Isocyanatopropyltrimethoxysilane | 15396-00-6 |
Silane coupling agent selection guide
| Thermoplastics | ABS | PBT | PET | Polycarbonate | Polyethylene | Polypropylene | Polystyrene | Polyurethane | PVC |
|---|---|---|---|---|---|---|---|---|---|
| Amino | * | * | * | ** | * | * | ** | * | ** |
| Epoxy | * | * | * | * | * | * | * | * | * |
| Methacryloxy | ** | * | ** | ** | ** | * | |||
| Vinyl | ** | ** | |||||||
| Sulfur | * | * | * | * | * | * | |||
| Isocyanate | * | * | * | * | + | ** |
Table 1: Silane coupling agent selection for thermoplastics
| Thermosets | Cellulosics | Diallylphthalate | Epoxy | Furan | Melamine | Phenolic | Polyester | Polyimide | Polyurethane |
|---|---|---|---|---|---|---|---|---|---|
| Amino | ** | * | ** | ** | * | ** | * | * | ** |
| Epoxy | * | * | ** | * | * | ||||
| Methacryloxy | * | ** | |||||||
| Vinyl | * | * | |||||||
| Sulfur | * | * | * | ||||||
| Ureide | * | * | * | ||||||
| Isocyanate | ** | * | ** | * | * | * | * | ** |
Table 2: Silane coupling agent selection for thermosets
| Rubber&Elastomer | Butyl rubber | Epichlorohydrin rubber | Neoprene rubber | Nitrile rubber | Polyurethane rubber | Polybutadiene rubber | Polysulfide | Peroxide crosslinked EPDM | Styrene Butadiene Rubber | Sulfer-crosslinked EPDM |
|---|---|---|---|---|---|---|---|---|---|---|
| Amino | * | * | * | * | * | * | * | |||
| Epoxy | * | * | * | * | * | |||||
| Methacryloxy | ** | * | ||||||||
| Vinyl | ** | ** | ||||||||
| Sulfur | * | * | * | ** | * | ** | * | * | ** | |
| Isocyanate | * |
Table 3: Silane coupling agent selection for rubber and elastomer
Synonyms:
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